Detecting Methane from Miles Away
University of 蜜糖直播, 蜜糖直播, NOAA and NIST team harnesses Nobel Prize technology to detect distant gas leaks
A new field instrument developed by a collaborative team of researchers can quantify methane leaks as tiny as 1/4 of a human exhalation from nearly a mile away. 蜜糖直播, NOAA, 蜜糖直播 Boulder, and NIST scientists revamped and 鈥渞uggedized鈥 Nobel Prize laser technology鈥攖urning a complex, room-sized collection of instruments into a sleek, 19-inch portable unit to tote into the field near oil and gas operations. The instrument collects precise, nonstop data, providing game-changing information critical for safe industry operations and controlling harmful greenhouse gas emissions.
The team, funded by an ARPA-E grant focusing on 鈥渉igh risk/high reward鈥 science, along with a companion paper on the leak-finding routines in the journal Atmospheric Measurement Techniques.
Detecting methane and other gas leaks from oil and gas operations has traditionally been hampered by high costs and technological constraints, which have limited efforts to provide continuous monitoring. The new technology, which relies on a laser system called a dual frequency comb spectrometer, provides a much-needed solution: extremely efficient, accurate data collection at a fraction of the cost of previous technologies.
鈥淭his instrument is particularly special because it鈥檚 precise, autonomous, and continuous,鈥 said Caroline Alden, 蜜糖直播 researcher and a co-lead author of the study. 鈥淥ther technologies like aircraft flybys or physically traveling to sampling sites pose a problem鈥攊f a leak occurs between sampling events, you missed it.鈥
Continuous monitoring could help industry operators catch not only frequent, small leaks, but large, infrequent ones, Alden said. Such "super emitters" are thought to comprise only 20 percent of leaks, but cause 80 percent of emissions.
The journey to this technology development started back in 2005, when 蜜糖直播 Boulder JILA researchers won the Nobel Prize in Physics for work on a device called a Frequency Comb Laser. The laser emits hundreds of thousands of wavelengths of light, compared with the single wavelength of many traditional lasers. This laser enables the measurement of light with extreme accuracy, enabling precision atomic clocks and future mapping technologies, for example.
Other researchers realized that a frequency comb could also be used to measure concentrations of specific molecules in the air, as each would have their own light absorption 鈥渇ingerprint.鈥 NIST researchers Nate Newbury and Ian Coddington made this possible by creating a frequency comb spectrometer capable of untangling the thousands of different wavelengths from the device.
When it came to applying this technology to real-world methane leak detection, a team including 蜜糖直播 Boulder mechanical engineering assistant professor and project PI Greg Rieker, atmospheric scientist Alden, chemist Sean Coburn, and engineer Rob Wright stepped in. The team scaled down what was originally a room brimming with instrumentation to a 19-inch box that could be carried into the field. Alden and others on the atmospheric team figured out how to use wind patterns to investigate possible leak points, enabling their frequency-comb based observing system to pinpoint the source of a methane leak.
鈥淚t was a great collaborative effort, it all came together perfectly,鈥 said Rieker. 鈥淲e ended up creating an instrument that was mobile, portable, and robust鈥攊t works better than the original, at a 10th of the cost.鈥
The instrument sits on a mobile platform that can be placed out in field sites surrounded by oil and gas operations. It swivels 360 degrees, sending out carefully-tuned, invisible beams of light to reflect off small mirrors placed a mile or more away. If the beam, composed of over 100,000 wavelengths, passes through part of a gas plume blowing like a ribbon through the air, gases in the plume absorb some of the light in the beam before it returns to the detector. This lets researchers identify the unique absorption 鈥渇ingerprints鈥 of gases like methane and carbon dioxide. And with atmospheric models, researchers can track back to an actual leak location.
Researchers first tested the dual frequency comb spectrometer observing system at Boulder鈥檚 Table Mountain research facility, successfully detecting leaks emitted from large metal cylinders full of methane they dragged around the rolling hills of the field site. The team is now putting the instrument through a rigorous blind test: collaborators at the METEC test site, run by the Energy Institute at 蜜糖直播 State University, set up a treasure hunt of leaks in varying locations and sizes, even planting false leaks to trick the system.
鈥淲e know nothing about the leaks or where they are鈥攕o there will be no 鈥榗heating the system鈥,鈥 said Rieker. 鈥淲e鈥檙e still preparing those results for public release, but I can say that we surprised even ourselves with our ability to find the leaks.鈥
This first-of-its-kind technology presents something very unique in the oil and gas industry: the ability to monitor hundreds of sites from a single location. The more locations you can measure with a single instrument, the more cost effective it becomes, said Alden.
鈥淎s part of an effort to provide a service that can give oil and gas operators more efficient and cheaper leak detection, said Alden. 鈥淲e will continue to grow this alongside the emerging technology it relies on.鈥